Dioxygen binding and activation by a new molybdenum (II) polynuclear complex
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چکیده
منابع مشابه
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We have used dioxygen, not artificial oxidants such as peracids, iodosylarenes, and hydroperoxides, in the generation of a mononuclear nonheme oxoiron(IV) complex, [Fe(IV)(TMC)(O)]2+ (TMC = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane), from its corresponding Fe(II) complex, [Fe(TMC)(CF3SO3)2]. The formation of oxoiron(IV) species by activating dioxygen was markedly dependent on iron(...
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متن کاملActivation of Dioxygen by Halocarbon Ions
Tandem mass spectrometry is used to show that low energy collisions of ionized halocarbenes, including CBr2 and CBrCl•+, with molecular oxygen lead to (i) decarbonation with formation of the dihalogen molecular cation and (ii) oxygenolysis yielding BrCO+. Both reactions may occur via the same ion-molecule addition product of molecular oxygen and the ionized carbene. Reaction is favored at low c...
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ژورنال
عنوان ژورنال: Journal of Molecular Catalysis
سال: 1980
ISSN: 0304-5102
DOI: 10.1016/0304-5102(80)85006-1